Homework 02

 

2. From Table 1. Consider the following:

 

Zeolite

Unit Cell composition

Secondary Building Unit

Largest Window Size ()

ZSM-23

Nan[AlnSi24-nO48].4H2O, n<2.5

 complex 5-1

5.5x5.9

gmelinite

(Na2,Ca)4[Al8Si16O48].24H2O

S6R, D6R, S4R, S8R

7.0x7.0

ZK-5

Na30[Al30Si66O192].98H2O

S6R, D6R, S4R, S8R

3.9x3.9

 

 

                 

2.1 Match the unit cell showing above to the zeolite listed in Table 1 and indicate number of T-atoms in the largest pore aperture (windows) (Unit cell represented by dot-line)

 

Unit Cell

Zeolite

T-ring

A

 

 

B

 

 

C

 

 

 

2.2 Which zeolite possess the lowest polarity, why?