Homework 02
2.
From Table 1. Consider the following:
|
Zeolite |
Unit Cell composition |
Secondary Building Unit |
Largest Window Size () |
|
ZSM-23 |
Nan[AlnSi24-nO48].4H2O, n<2.5 |
complex 5-1 |
5.5x5.9 |
|
gmelinite |
(Na2,Ca)4[Al8Si16O48].24H2O |
S6R, D6R, S4R, S8R |
7.0x7.0 |
|
ZK-5 |
Na30[Al30Si66O192].98H2O |
S6R, D6R, S4R, S8R |
3.9x3.9 |
2.1 Match the unit cell
showing above to the zeolite listed in Table 1 and indicate number of T-atoms
in the largest pore aperture (windows) (Unit cell represented by dot-line)
|
Unit Cell |
Zeolite |
T-ring |
|
A |
|
|
|
B |
|
|
|
C |
|
|
2.2 Which zeolite possess the
lowest polarity, why?